steric and electronic factors

steric and electronic factors
Макаров: стерический и электронный факторы

Универсальный англо-русский словарь. . 2011.

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  • coordination compound — Chem. complex (def. 10). Also called coordination complex. * * * ▪ chemistry Introduction  any of a class of substances with chemical structures in which a central metal atom is surrounded by nonmetal atoms or groups of atoms, called ligands… …   Universalium

  • Catenation — is the ability of a chemical element to form a long chain like structure via a series of covalent bonds. Catenation occurs most readily in carbon, which forms covalent bonds with other carbon atoms. Catenation is the reason for the presence of a… …   Wikipedia

  • Polyproline helix — In proteins, a left handed polyproline II helix (PPII, poly Pro II) is formed when sequential residues all adopt (φ,ψ) backbone dihedral angles of roughly ( 75°, 150°) and have trans isomers of their peptide bonds. Similarly, a more compact right …   Wikipedia

  • Radical-nucleophilic aromatic substitution — or SRN1 in organic chemistry is a type of substitution reaction in which a certain substituent on an aromatic compound is replaced by a nucleophile through an intermediary free radical species:The substituent X is a halide and nucleophiles can be …   Wikipedia

  • Tributylphosphine — chembox new ImageFile=tributylphosphine.png ImageSize=150px ImageFile1=Tributylphosphine 3D vdW.png IUPACName=Tributylphosphine Section1 = Chembox Identifiers CASNo=998 40 3 EINECS=213 651 2 SMILES=CCCCP(CCCC)CCCC DispInChI=1/C12H27P/c1 4 7 10… …   Wikipedia

  • reaction mechanism — Introduction       in chemical reactions (chemical reaction), the detailed processes by which chemical substances are transformed into other substances. The reactions themselves may involve the interactions of atoms (atom), molecules (molecule),… …   Universalium

  • Cluster chemistry — In chemistry, a cluster is an ensemble of bound atoms intermediate in size between a molecule and a bulk solid. Clusters exist of diverse stoichiometries and nuclearities. For example, carbon and boron atoms form fullerene and borane clusters,… …   Wikipedia

  • Hyperconjugation — In organic chemistry, hyperconjugation is the interaction of the electrons in a sigma bond (usually C–H or C–C) with an adjacent empty (or partially filled) non bonding p orbital or antibonding π orbital or filled π orbital, to give an extended… …   Wikipedia

  • Polythiophene — The monomer repeat unit of unsubstituted polythiophene …   Wikipedia

  • Amine — For other uses, see Amine (disambiguation). Primary amine Secondary amine Tertiary amine …   Wikipedia

  • Aldol reaction — The aldol reaction is a powerful means of forming carbon–carbon bonds in organic chemistry.[1][2][3] Discovered independently by …   Wikipedia


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